I. Isingeniso Somkhiqizo Lo mkhiqizo uyisikhubazi-oksijeni esisebenza kakhulu esenziwe yi-Shandong Zhonglian Chemistry Co., Ltd. yodwa. Kuyinto esetshenziswa ngokwezifiso eyenzelwe izikhubazi-oksijeni, ehlose ukuxazulula izinkinga eziyinhloko embonini yezikhubazi-oksijeni: "umthamo onganele wokumunca umoya-mpilo obangelwa ukwakheka kwezimbotshana okungalungile, impilo emfushane ngenxa yokumelana nomswakama okungalungile, kanye nomphumela wokukhubaza i-oksijeni ongalingani ngenxa yokusabalala okungalungile". Ngokusekelwe ekulawuleni okunembayo kosayizi wezinhlayiya zesayizi ye-nano nokwakheka kwezimbotshana, kuhlanganiswe nezinqubo zokulungiselela ezithuthukisiwe njengendlela ye-sol-gel kanye nobuchwepheshe bokugaya umoya obulungisiwe, lo mkhiqizo awuxazululi kuphela izinkinga eziyinhloko ze-silicon dioxide yakudala ekusetshenzisweni kwezikhubazi-oksijeni kodwa futhi unokusebenza okuhle kakhulu kokusiza ukumunca umoya-mpilo, ukumelana nomswakama, nokuqina komqulu. Isetshenziswa kabanzi ekudleni, emithini, ekudleni kwezilwane, ezintweni zikagesi, kumishini enembayo nezinye izindawo ezidinga ukukhubaza i-oksijeni nokugcina, futhi ithunyelwa eYurophu, eMelika, eNingizimu-mpumalanga Asia naseMiddle East kanye nezinye izimakethe zamazwe ngamazwe. II. Izinzuzo Eziyinhloko Zomkhiqizo 1. Ukwakheka Kwezimbotshana Okulungisiwe Nomthamo Omkhulu Wokusiza Ukumunca Umoya-mpilo Lo mkhiqizo unendawo eqondile (≥400 m²/g) nokwakheka kwezimbotshana okungalawulwa (ububanzi bezimbotshana 3-60 nm), okungakwazi ukumunca umswakama emoyeni ngenkathi unikeza isisekelo esiqinile sezinto ezikhubaza i-oksijeni (njengepowdara yensimbi, i-carbon esebenzayo), kuthuthukisa kakhulu ukusebenza nomthamo wokumunca umoya-mpilo wesikhubazi-oksijeni. Indlela yayo eyinhloko isekelwe ekusebenziseni indlela ye-template kanye nendlela ye-sol-gel ethuthukisiwe ukulawula ngokunembayo inqubo yokuqala nokukhula kwamatshe amatshe e-silica, ukufeza ukufanisana okunembayo komthamo wezimbotshana nokusatshalaliswa kwezimbotshana nezinhlelo ezahlukene zezikhubazi-oksijeni. Lokhu kuthuthukisa ngempumelelo indawo yokuxhumana phakathi kwezinto ezikhubaza i-oksijeni nomoya-mpilo, kusheshe isivinini sokuphendula sokukhubaza i-oksijeni, futhi kuqinisekise umphumela osheshayo nowonke wokukhubaza i-oksijeni. 2. Ukuhlanzeka Okuphezulu Nokumelana Nomswakama Okuhle Kakhulu Ngokulandela ngokuqinile izidingo eziphakeme zezinto ezisiza izikhubazi-oksijeni, lo mkhiqizo unokuhlanzeka okungu-≥99% kanye nokuqukethwe okuphansi kakhulu kwezinto ezingcolile (insimbi esindayo lead ≤0.001%, arsenic ≤0.0003%), okuhambisana ngokuphelele namazinga okudla okuphezulu, imithi, namazinga aphezulu amazwe ngamazwe. Yonke inqubo yokukhiqiza isebenzisa ukuvikelwa ngegazi elingenamoya kanye nobuchwepheshe bokulungiselela izinto ezingavuthiwe eziphakeme kakhulu, okugwema ngokuyisisekelo ukungeniswa kwezinhlayiya ezingcolile ezingathinta umphumela wokukhubaza i-oksijeni noma zibangele ukungcola. Inokumelana nomswakama okuhle kakhulu nokuqina kwemvelo, ingagcina ubuqotho bomqulu ezindaweni ezinomswakama (umswakama ohlobene ≤80%), ayimunci umswakama futhi ayihlangani, futhi iqinisekisa ngempumelelo ukusebenza okuzinzile kwesikhathi eside kwesikhubazi-oksijeni. 3. Ukusabalala Okuhle Kakhulu Nokuhambisana Nezinto Ezikhubaza i-Oksijeni Ngokusekelwe ekusatshalalisweni kosayizi wezinhlayiya zesayizi ye-nano okuhleliwe (D50=2-12 μm) nobuchwepheshe bokuguqula ubuso, lo mkhiqizo unokusebenza okuhle kakhulu kokusabalala futhi ungahlanganiswa ngokulinganayo nezinto ezahlukene ezikhubaza i-oksijeni (njengepowdara yensimbi, i-carbon esebenzayo, i-zeolite, njll.). Ingakha uhlelo lokusabalala oluqinile nezingxenye ezikhubaza i-oksijeni, igweme ngempumelelo ukuhlanganiswa kwezinto ezikhubaza i-oksijeni ngesikhathi sokugcina nokusebenzisa, iqinisekise ukuthi zonke izingxenye ezikhubaza i-oksijeni zingathintana ngokugcwele nomoya-mpilo. Kuthuthukisa izinga lokusetshenziswa kwezinto ezikhubaza i-oksijeni ngaphezu kuka-35%, futhi kuqinisekisa ukulingana nokuqina komphumela wokukhubaza i-oksijeni kuso sonke isikhala sokupakisha. 4. Amandla Okwenza Ngokwezifiso Avumelayo Isekela izinsizakalo zokwenza ngokwezifiso ezibhekiswe kumapharamitha abalulekile njengosayizi wezinhlayiya (2-100 μm), indawo eqondile (300-900 m²/g) nokwakheka kwezimbotshana (3-100 nm). Ngokwezici zenqubo nezidingo zokusebenza zezimo ezahlukene zokusebenzisa izikhubazi-oksijeni (njengokupakisha ukudla, ukupakisha imithi, ukugcina izinto zikagesi, ukugcina izinto zokudla kwezilwane), inikeza izixazululo zomkhiqizo ezivumelana kakhulu. Ngokwesibonelo, ezikhubazini-oksijeni zokudla, ingenza ngokwezifiso i-silica enosayizi omncane wezinhlayiya, ehlanzekile ukuze kuqinisekiswe ukuphepha nokusabalala; ezikhubazini-oksijeni zezinto zikagesi, inganikeza imikhiqizo evimbela umswakama nokuqina okuphezulu ukuze kugwenywe ukulimala komswakama ezintweni zikagesi. 5. Isiqinisekiso Sesevisi Yezobuchwepheshe Yesigaba Esigcwele Inikeza ukwesekwa kwezobuchwepheshe okuyindawo eyodwa okuhlanganisa ngaphambi kokuthengisa, ngesikhathi sokuthengisa, nangemva kokuthengisa. Ngaphambi kokuthengisa, inganikeza izinsizakalo zokuhlola amasampula enziwe ngokwezifiso kanye nokuhlola ukusebenza kokukhubaza i-oksijeni; ngesikhathi sokuthengisa, inikeza isiqondiso sezobuchwepheshe ngesilinganiso sokuhlanganisa sezinto ezikhubaza i-oksijeni ne-silica, kanye nesiqondiso senqubo yokusebenzisa; ngemva kokuthengisa, ithimba lochwepheshe le-R&D lilandelela umphumela wokusebenzisa, lixazulule izinkinga zobuchwepheshe njengokuncipha kokusebenza kokukhubaza i-oksijeni nokuhlanganiswa, futhi lulungise amapharamitha omkhiqizo ngokusekelwe kumpendulo yomsebenzisi ukuze kuqinisekiswe ukusebenza okuphezulu kwesikhubazi-oksijeni. III. Isiqinisekiso Samandla Okukhiqiza I-Shandong Zhonglian Chemistry Co., Ltd., eyasungulwa ngo-2022, iyibhizinisi lobuchwepheshe obuphezulu eligxile ku-R&D nokukhiqizwa kwezinto zamakhemikhali eziphezulu, nelungelo lokungenisa nokuthumela ngaphandle elizimele kanye nezitifiketi eziningi (kuhlanganise nesitifiketi somkhiqizo wokudla, imithi). Le nkampani inezimvume ezimbili eziyinhloko emkhakheni wokulungiselela i-silica, okuhlanganisa idivayisi yokugaya umoya ephezulu yokukhiqiza i-silica kanye nohlelo lokulungisa oluhlakaniphile lwezinqubo zokuphendula nge-electrochemical, okunikeza ukwesekwa okuqinile kwezobuchwepheshe ekuthuthukisweni kwekhwalithi yomkhiqizo. Isisekelo sokukhiqiza samukela ukulawulwa kwenqubo eyenziwe kahle, sihlinzekwe ngemishini yokuhlola ethuthukisiwe njenge-laser particle size analyzers, i-specific surface area and pore size analyzers, kanye ne-X-ray fluorescence spectrometers, futhi siye sakha izinqubo zokuhlola ezigcwele eziyi-18 ezihlanganisa ukuhlanzwa kwezinto ezingavuthiwe, ukuhlanganiswa kwesikhashana kuze kube ukuhlolwa komkhiqizo oqediwe. Ithole isitifiketi se-ISO9001 quality management system kanye nesitifiketi sokuphepha sokudla, ukufeza ukulawulwa okujwayelekile kwekhethini lonke kusuka ku-R&D, ukukhiqiza kuze kube ukuhlolwa kwekhwalithi. IV. Izincazelo Zokupakisha Nokuthutha 1. Izincazelo Zokupakisha Ezejwayelekile Ukusebenzisa umklamo wokupakisha ojwayelekile ohambisana nezidingo zokupakisha zokudla nemithi, okunikeza izinketho zokupakisha izikhwama zamaphepha e-kraft angu-25kg kanye namathini ensimbi agalelwe u-50kg ukuze kuhlangatshezwane nezidingo ezahlukene zezinani le-oda nezokuthutha. Izinto zokupakisha zenziwe ngezinto ezingenasici, ezinganobuthi futhi ezingangcoli ukuze kugwenywe ukusabela kwamakhemikhali nomkhiqizo futhi kuqinisekiswe ukuphepha nokuhlanzeka komkhiqizo. 2. Umklamo Ochwepheshe Wokuvimbela Umswakama Nokuvimbela Ukungcola Ukuze kuqinisekiswe ukuqina komkhiqizo ngesikhathi sokuthutha nokugcina, kusebenziswe isixazululo sokuvikela esiphindwe kabili: umngcele wangaphakathi usebenzisa ifilimu ye-PE yokudla enobubanzi obungu-≥0.08mm ukuze kuvalwe umswakama, kanti umngcele wangaphandle usebenzisa izikhwama ezilukiwe eziqinile noma amathini ensimbi agalelwe ukuze kuvikelwe ukushayisana nokungcola. Kwimikhiqizo ethunyelwa ngaphandle, kusetshenziswa ukupakisha kwe-vacuum + ukuthunyelwa kwesitsha ukuze kugwenywe ukungena komswakama nokungcola okuhlangene ngesikhathi sokuthutha ibanga elide, kuqinisekiswe ukuthi umkhiqizo ugcina ukusebenza kwawo kwasekuqaleni lapho ufika kumakhasimende. 3. Izidingo Zokugcina Nokuthutha - Izimo zokugcina: Kufanele zigcinwe endaweni epholile, eyomile futhi enomoya omuhle, kugwenywe ukukhanya kwelanga okuqondile, izinga lokushisa eliphezulu (≥40℃) kanye nendawo enomswakama (umswakama ohlobene ≤70%), futhi kufanele zigcinwe ngokuhlukile nezinto ezivutha kalula, izinsipho ezinamandla nezi-alkali; - Impilo yeshalofu: izinyanga ezingama-36 ngaphansi kwezimo zokugcina ezifanele; - Izici zokuthutha: Lo mkhiqizo uyikhemikhali engadali ingozi, usekela ukuthunyelwa ngolwandle, ngomhlaba, ngomoya nezinye izindlela zokuthutha, futhi ungadluliselwa ngokuphepha ezindaweni ezibekwe ngamakhasimende asekhaya naphesheya. Ngesikhathi sokuthutha, kuyadingeka ukugwema ukushayisana okunamandla, imvula nomswakama. 4. Ukulebula Okujwayelekile Wonke umthwalo wokupakisha womkhiqizo ubhalwe ngokuqinile ngolwazi lomkhiqizo njengobuntu besikhubazi-oksijeni, ukuhlanzeka, indawo eqondile, usayizi wezimbotshana, inombolo yomthwalo wokukhiqiza kanye nempilo yeshalofu; ngesikhathi esifanayo, ngokwemibandela yemithetho yezimakethe ezahlukene zokuthumela ngaphandle kanye nezindawo zokusebenzisa (ukudla, imithi), izilebula zezilimi eziningi kanye namashidi emininingwane yokuphepha (SDS) angakwenziwa ngokwezifiso ukuze kuqinisekiswe ukuhambisana namazinga okufinyelela emakethe endawo kanye nemithetho yokuphepha. V. Izindawo Zokusebenzisa Ezisebenzayo Lo mkhiqizo usetshenziswa kabanzi emkhakheni wezikhubazi-oksijeni, uhlanganisa izimboni eziningi nezigameko ezidinga ukukhubaza i-oksijeni, ukuvimbela umswakama nokugcina: 1. Imboni Yokudla Isetshenziswa njengento esiza izikhubazi-oksijeni zokudla, esebenza ezintweni ezibhakiwe, amantongomane, izithelo ezomisiwe, imikhiqizo yenyama, amaswidi, imikhiqizo yezinhlamvu namafutha, njll. Isiza izinto ezikhubaza i-oksijeni ukuba zimunce ngokushesha umoya-mpilo esikhwameni, igweme ukubola kokudla, ukubola, ukushintsha umbala nokubola, yandise impilo yokudla izikhathi ezi-2-3, futhi igcine ukunambitheka kwasekuqaleni nekhwalithi yokudla. 2. Imboni Yemithi Isetshenziswa ezikhubazini-oksijeni zokupakisha imithi, okuhlanganisa amaphilisi, amakhepsuli, izimpushana, imijovo nezinye izimikhiqizo zemithi. Ingakwazi ukususa ngempumelelo umoya-mpilo esikhwameni, igweme ukubola kwezithako zemithi, iqinisekise ukusebenza nokuqina kwemithi, futhi ihlangabezane nezidingo eziqinile zekhwalithi zemboni yemithi. 3. Imboni Yokudla Kwezilwane Isetshenziswa njengento esiza izikhubazi-oksijeni zokudla kwezilwane, esebenza ezinhlobonhlobo zezinto zokudla ezihlanganisiwe, izithako zokudla kwezilwane kanye nezokudla kwezilwane zasemanzini. Ivimbela ukubola kokudla kwezilwane, ukubola nokulahleka kwezakhamzimba ngesikhathi sokugcina, ithuthukisa ikhwalithi yokudla kwezilwane, futhi igweme izifo zezilwane ezibangelwa ukudla kwezilwane okubolile. 56. Imboni Yezinto Zikagesi Nemishini Enembayo Isetshenziswa ezikhubazini-oksijeni zezinto zikagesi nemishini enembayo (njengezinhlamvu, izinzwa, imitha enembayo). Ayisusi kuphela umoya-mpilo esikhwameni ukuze kugwenywe ukugqwala kwezingxenye zensimbi kodwa futhi inokusebenza okuhle kakhulu kokuvimbela umswakama, igweme ukulimala komswakama ezintweni zikagesi nemishini enembayo, iqinisekise ukusebenza kwayo okujwayelekile nempilo. VI. Isiphetho I-silicon dioxide ye-Shandong Zhonglian Chemistry eyenzelwe izikhubazi-oksijeni ibekwe enhliziyweni yokuthi "kuthuthukiswe ukusebenza kokukhubaza i-oksijeni, kwandiswe isikhathi sokugcina futhi kuqinisekiswe ukuphepha komkhiqizo". Ngokusekelwe kubuchwepheshe bokulungiselela obusha, uhlelo oluqinile lokulawula ikhwalithi kanye nethimba lezobuchwepheshe elisebenzayo, inikeza izixazululo eziyindawo eyodwa ezisiza izikhubazi-oksijeni ezinkampanini ezimbonini zokudla, zemithi, zezilwane, zikagesi nezinye izimboni. Le nkampani izibophezele ekuthuthukiseni imboni yezikhubazi-oksijeni ngemikhiqizo esezingeni eliphezulu futhi yamukela ngobuqotho imibuzo kanye nokubambisana okuvela kumakhasimende asekhaya naphesheya.