I. Isingeniso Somkhiqizo Lo mkhiqizo uyisikhubazi-oksijeni esisebenza kakhulu esenziwe yi-Shandong Zhonglian Chemistry Co., Ltd. yodwa. Kuyinto esetshenziswa ngokwezifiso eyenzelwe izikhubazi-oksijeni, ehlose ukuxazulula izinkinga eziyinhloko embonini yezikhubazi-oksijeni: "umthamo onganele wokumunca umoya-mpilo ngenxa yesakhiwo sezimbotshana esibi, impilo emfushane ngenxa yokumelana nomswakama okungalungile, nomphumela wokukhubaza i-oksijeni ongalingani ngenxa yokuhlakazeka okungalungile". Ngokusekelwe ekulawuleni okunembayo kosayizi wamachashaza esigaba se-nano nesakhiwo sezimbotshana, kuhlanganiswe nezinqubo zokulungiselela ezithuthukisiwe njengendlela ye-sol-gel kanye nobuchwepheshe obuthuthukisiwe bokugaya ngomoya, lo mkhiqizo awuxazululi kuphela izinkinga eziyinhloko ze-silicon dioxide yakudala ekusetshenzisweni kwezikhubazi-oksijeni, kodwa futhi unokusebenza okuhle kakhulu kokusiza ukumunca umoya-mpilo, ukumelana nomswakama, nokuzinza kwesakhiwo. Ivame ukusetshenziswa ekudleni, emithini, ekudleni kwezilwane, ezikagesi, kumishini enembayo nezinye izindawo ezidinga ukukhubaza i-oksijeni nokugcina, futhi ithunyelwa eYurophu, eMelika, eNingizimu-mpumalanga Asia naseMiddle East kanye nezinye izimakethe zamazwe ngamazwe. II. Izinzuzo Eziyinhloko Zomkhiqizo 1. Isakhiwo Sezimbotshana Esithuthukisiwe kanye Nomthamo Omkhulu Wokusiza Ukumunca Umoya-mpilo Lo mkhiqizo unendawo eqondile (≥400 m²/g) kanye nesakhiwo sezimbotshana esilawulwayo (ububanzi bezimbotshana 3-60 nm), esingakwazi ukumunca kahle umswakama emoyeni ngenkathi sihlinzeka ngesithwali esizinzile sezinto ezikhubaza i-oksijeni (njengomgqomo wensimbi, ukhola olusebenzayo), sithuthukisa kakhulu ukusebenza nomthamo wokumunca umoya-mpilo wesikhubazi-oksijeni. Indlela yayo eyinhloko isekelwe ekusebenziseni indlela ye-template kanye nendlela ye-sol-gel ethuthukisiwe ukulawula ngokunembayo inqubo yokuqala nokukhula kwamatshe amatshe e-silica, ukufeza ukufanisana okunembayo komthamo wezimbotshana nokusatshalaliswa kwezimbotshana nezinhlelo ezahlukene zezikhubazi-oksijeni. Lokhu kuthuthukisa ngempumelelo indawo yokuxhumana phakathi kwezinto ezikhubaza i-oksijeni nomoya-mpilo, kusheshe isivinini sokuphendula sokukhubaza i-oksijeni, futhi kuqinisekise umphumela osheshayo nowuphelele wokukhubaza i-oksijeni. 2. Ukuhlanzeka Okuphezulu Nokumelana Nomswakama Okuhle Kakhulu Ngokulandela ngokuqinile izidingo eziphakeme zezinto ezisizayo zezikhubazi-oksijeni, lo mkhiqizo unokuhlanzeka okungu-≥99% kanye nokuqukethwe okuphansi kakhulu kwezinto ezingcolile (insimbi esindayo ≤0.001%, i-arsenic ≤0.0003%), uhambisana ngokuphelele namazinga okudla okuphezulu, imithi, kanye namazinga aphezulu amazwe omhlaba. Yonke inqubo yokukhiqiza isebenzisa ukuvikelwa ngegazi elingenamoya kanye nobuchwepheshe bokulungiselela izinto ezingavuthiwe eziphakeme kakhulu, okugwema ngokuyisisekelo ukungena kwezinhlayiya ezingcolile ezingathinta umphumela wokukhubaza i-oksijeni noma ukubangela ukungcola. Inokumelana nomswakama okuhle kakhulu kanye nokuzinza kwemvelo, ingagcina ubuqotho besakhiwo ezindaweni ezinomswakama (umswakama ohlobene ≤80%), ayimunci umswakama futhi ayihlangani, futhi iqinisekisa ngempumelelo ukusebenza okuzinzile kwesikhathi eside kwesikhubazi-oksijeni. 3. Ukuhlakazeka Okuhle Kakhulu Nokuhambisana Nezinto Ezikhubaza i-Oksijeni Ngokusekelwe ekusatshalalisweni kosayizi wamachashaza esigaba se-nano okuthuthukisiwe (D50=2-12 μm) kanye nobuchwepheshe bokuguqula ubuso, lo mkhiqizo unokusebenza okuhle kakhulu kokuhlakazeka futhi ungahlanganiswa ngokulinganayo nezinto ezahlukene ezikhubaza i-oksijeni (njengomgqomo wensimbi, ukhola olusebenzayo, i-zeolite, njll.). Ingakha uhlelo lokuhlakazeka oluzinzile ngezinto ezikhubaza i-oksijeni, igweme ngempumelelo ukuhlanganiswa kwezinto ezikhubaza i-oksijeni ngesikhathi sokugcina nokusebenzisa, iqinisekise ukuthi zonke izinto ezikhubaza i-oksijeni zingathintana ngokugcwele nomoya-mpilo. Ithuthukisa izinga lokusetshenziswa kwezinto ezikhubaza i-oksijeni ngaphezu kuka-35%, futhi iqinisekisa ukulingana nokuzinza komphumela wokukhubaza i-oksijeni kuso sonke isikhala sokupakisha. 4. Amandla Okwenza Ngokwezifiso Avumelayo Isekela izinsizakalo zokwenza ngokwezifiso ezibhekiswe kumapharamitha ayinhloko njengosayizi wamachashaza (2-100 μm), indawo eqondile (300-900 m²/g) kanye nesakhiwo sezimbotshana (3-100 nm). Ngokwezici zenqubo nezidingo zokusebenza zezimo ezahlukene zokusebenzisa izikhubazi-oksijeni (njengokupakisha ukudla, ukupakisha imithi, ukugcina izinto zikagesi, ukugcina izinto zokudla kwezilwane), ihlinzeka ngezixazululo zomkhiqizo ezivumelana kakhulu. Ngokwesibonelo, ezikhubazini-oksijeni zokudla, ingenza ngokwezifiso i-silica enosayizi wamachashaza ocolekile, ehlanzekile ukuze kuqinisekiswe ukuphepha nokuhlakazeka; ezikhubazini-oksijeni zezinto zikagesi, inganikeza imikhiqizo evimbela umswakama futhi ezimile kakhulu ukugwema ukulimala komswakama ezintweni zikagesi. 5. Isiqinisekiso Sesevisi Yezobuchwepheshe Esigcwele Isikhathi Iyanikeza ukwesekwa kwezobuchwepheshe okuyindawo eyodwa okuhlanganisa ngaphambi kokuthengisa, ngesikhathi sokuthengisa, nangemva kokuthengisa. Ngaphambi kokuthengisa, inganikeza izinsizakalo zokuhlola amasampula ngokwezifiso kanye nokuhlola ukusebenza kokukhubaza i-oksijeni; ngesikhathi sokuthengisa, inikeza isiqondiso sezobuchwepheshe ngesilinganiso sokuhlanganisa izinto ezikhubaza i-oksijeni ne-silica, kanye nesiqondiso senqubo yokusebenzisa; ngemva kokuthengisa, ithimba lochwepheshe le-R&D lilandelela umphumela wokusebenzisa, lixazulule izinkinga zobuchwepheshe njengokuncipha kokusebenza kokukhubaza i-oksijeni nokuhlanganiswa, futhi luthuthukise amapharamitha omkhiqizo ngokusekelwe empendulweni yomsebenzisi ukuze kuqinisekiswe ukusebenza okuphezulu kwezikhubazi-oksijeni. III. Isiqinisekiso Samandla Okukhiqiza I-Shandong Zhonglian Chemistry Co., Ltd., eyasungulwa ngo-2022, iyibhizinisi lobuchwepheshe obuphezulu eligxile ku-R&D kanye nokukhiqizwa kwezinto zamakhemikhali eziphezulu, enamalungelo okungenisa nokuthumela ngaphandle azimele kanye nezitifiketi eziningi (kuhlanganise nesitifiketi somkhiqizo wokudla, imithi). Le nkampani inezimvume ezimbili eziyinhloko emkhakheni wokulungiselela i-silica, okuhlanganisa idivayisi yokugaya ngomoya ephezulu yokukhiqiza i-silica kanye nohlelo lokuthuthukisa oluhlakaniphile lwezinqubo zokuphendula nge-electrochemical, ihlinzeka ngokwesekwa okuqinile kwezobuchwepheshe ekuthuthukisweni kwekhwalithi yomkhiqizo. Isisekelo sokukhiqiza samukela ukulawulwa kwenqubo eyenziwe yaba yinhle, sifakwe imishini yokuhlola ethuthukisiwe njenge-laser particle size analyzers, specific surface area and pore size analyzers, kanye ne-X-ray fluorescence spectrometers, futhi siye sakha izinqubo zokuhlola ezigcwele eziyi-18 ezihlanganisa ukuhlanzwa kwezinto ezingavuthiwe, ukuhlanganiswa kwesikhashana kuze kube ukuhlolwa komkhiqizo oqediwe. Ithole isitifiketi sohlelo lokuphatha ikhwalithi lwe-ISO9001 kanye nesitifiketi sokuphepha sokudla, ukufeza ukulawulwa okujwayelekile kuyo yonke indawo kusuka ku-R&D, ukukhiqiza kuze kube ukuhlolwa kwekhwalithi. IV. Izincazelo Zokupakisha Nokuthutha 1. Izincazelo Zokupakisha Ezijwayelekile Ukusebenzisa umklamo wokupakisha ojwayelekile ohambisana nezidingo zokupakisha zokudla nemithi, ihlinzeka ngezinketho zokupakisha izikhwama zamaphepha e-kraft eziyi-25kg kanye namadreyi ensimbi agalelweyo angama-50kg ukuze kuhlangatshezwane nezidingo ezahlukene zezinani le-oda nezokuthutha. Izinto zokupakisha zonke zenziwe ngezinto ezingasebenzi, ezinganobuthi futhi ezingangcoli ukuze kugwenywe ukusabela kwamakhemikhali nomkhiqizo futhi kuqinisekiswe ukuphepha nokuhlanzeka komkhiqizo. 2. Umklamo Ochwepheshe Wokuvimbela Umswakama Nokuvimbela Ukungcola Ukuze kuqinisekiswe ukuzinza komkhiqizo ngesikhathi sokuthutha nokugcina, kusebenziswe isixazululo sokuvikela esiphindwe kabili: umngqondo wangaphakathi usebenzisa ifilimu ye-PE yokudla enobubanzi obungu-≥0.08mm ukuze kuvalwe umswakama, kanti umngqondo wangaphandle usebenzisa izikhwama ezilukiwe eziqinile noma amadreyi ensimbi agalelweyo ukuze kuvikelwe ukushayisana nokungcola. Emikhiqizweni ethunyelwa ngaphandle, kusetshenziswa ukupakisha kwe-vacuum + ukuthunyelwa kwesitsha ukuze kugwenywe ukungena komswakama nokungcola okuhlangene ngesikhathi sokuthutha ibanga elide, kuqinisekiswe ukuthi umkhiqizo ugcina ukusebenza kwawo kwasekuqaleni lapho ufinyelela kumakhasimende. 3. Izidingo Zokugcina Nokuthutha - Izimo zokugcina: Kufanele zigcinwe endaweni epholile, eyomile futhi enomoya omuhle, kugwenywe ukukhanya kwelanga okuqondile, izinga lokushisa eliphezulu (≥40℃) kanye nendawo enomswakama (umswakama ohlobene ≤70%), futhi kufanele zigcinwe ngokuhlukile nezinto ezikhubaza i-oksijeni, izinsipho ezinamandla kanye ne-alkalis; - Impilo yeshalofu: izinyanga ezingama-36 ngaphansi kwezimo zokugcina ezifanele; - Izici zokuthutha: Lo mkhiqizo uyikhemikhali engayona ingozi, usekela ukuthunyelwa ngolwandle, ngomhlaba, ngomoya nezinye izindlela zokuthutha, futhi ungadluliselwa ngokuphepha ezindaweni ezibekwe ngamakhasimende asekhaya naphesheya. Ngesikhathi sokuthutha, kuyadingeka ukugwema ukushayisana kakhudlwana, imvula nomswakama. 4. Ukulebula Okujwayelekile Wonke umthwalo womkhiqizo wokupakisha uphawulwe ngokuqinile ngolwazi lomkhiqizo njengobuntu besikhubazi-oksijeni, ukuhlanzeka, indawo eqondile, usayizi wezimbotshana, inombolo yomthwalo wokukhiqiza kanye nempilo yeshalofu; ngesikhathi esifanayo, ngokwemibandela yemithetho yezimakethe ezahlukene zokuthumela ngaphandle kanye nezindawo zokusebenzisa (ukudla, imithi), izilebula zezilimi eziningi kanye namashidi emininingwane yokuphepha (SDS) angakwazi ukwenziwa ngokwezifiso ukuze kuqinisekiswe ukuhambisana namazinga okufinyelela emakethe endawo kanye nemithetho yokuphepha. V. Izindawo Zokusebenzisa Ezisebenzayo Lo mkhiqizo usetshenziswa kabanzi emkhakheni wezikhubazi-oksijeni, uhlanganisa izimboni eziningi nezinye izimo ezidinga ukukhubaza i-oksijeni, ukuvimbela umswakama nokugcina: 1. Imboni Yokudla Isetshenziswa njengento esizayo yezikhubazi-oksijeni zokudla, esebenza ezintweni ezibhakiwe, amantongomane, izithelo ezomisiwe, imikhiqizo yenyama, amaswidi, imikhiqizo yezinhlamvu namafutha, njll. Isiza izinto ezikhubaza i-oksijeni ukuba zimunce ngokushesha umoya-mpilo ekupakisheni, igweme ukubola kokudla, ukubola, ukushintsha umbala nokubola, yandise impilo yokudla izikhathi ezi-2-3, futhi igcine ukunambitheka kwasekuqaleni kanye nekhwalithi yokudla. 2. Imboni Yemithi Isetshenziswa ezikhubazini-oksijeni zokupakisha imithi, okuhlanganisa amaphilisi, amakhasimende, izimpushana, imijovo nezinye izimikhiqizo zemithi. Ingakwazi ukususa ngempumelelo umoya-mpilo ekupakisheni, igweme ukubola kwezithako zemithi, iqinisekise ukusebenza nokuzinza kwemithi, futhi ihlangabezane nezidingo zekhwalithi eziqinile zemboni yemithi. 3. Imboni Yokudla Kwezilwane Isetshenziswa njengento esizayo yezikhubazi-oksijeni zokudla kwezilwane, esebenza ezinhlobonhlobo zezinto zokudla ezihlanganisiwe, izithako zokudla kwezilwane kanye nezokudla kwezilwane zasemanzini. Ivimbela ukubola kokudla kwezilwane, ukubola kanye nokulahleka kwezakhamzimba ngesikhathi sokugcina, ithuthukisa ikhwalithi yokudla kwezilwane, futhi igweme izifo zezilwane ezibangelwa ukudla kwezilwane okubolile. 49. Imboni Yezikagesi Nemishini Enembayo Isetshenziswa ezikhubazini-oksijeni zezinto zikagesi nemishini enembayo (njengama-chip, izinzwa, imitha enembayo). Ayisusi kuphela umoya-mpilo ekupakisheni ukuze kugwenywe ukugqwala kwezingxenye zensimbi, kodwa futhi inokusebenza okuhle kakhulu kokuvimbela umswakama, igweme ukulimala komswakama ezintweni zikagesi nemishini enembayo, iqinisekise ukusebenza kwayo okujwayelekile kanye nempilo yesevisi. VI. Isiphetho I-silicon dioxide ye-Shandong Zhonglian Chemistry eyenzelwe izikhubazi-oksijeni ibekwe enkabeni ye-"ukuthuthukisa ukusebenza kokukhubaza i-oksijeni, ukwandisa isikhathi sokugcina kanye nokuqinisekisa ukuphepha komkhiqizo". Ngokusekelwe kubuchwepheshe bokulungiselela obusha, uhlelo oluqinile lokulawula ikhwalithi kanye nethimba lezobuchwepheshe elichwepheshile, ihlinzeka ngezixazululo eziyindawo eyodwa zezikhubazi-oksijeni ezinkampanini ezimbonini zokudla, zemithi, zezokudla kwezilwane, zezikagesi nezinye izimboni. Le nkampani izibophezele ekuthuthukiseni imboni yezikhubazi-oksijeni ngemikhiqizo esezingeni eliphezulu futhi yamukela ngobuqotho imibuzo kanye nokubambisana okuvela kumakhasimende asekhaya naphesheya.