I. Isingeniso Somkhiqizo Lo mkhiqizo uyisikhubazi-oksijini esisebenza kakhulu esenziwe yi-Shandong Zhonglian Chemistry Co., Ltd. yodwa. Kuyinto esetshenziswayo eyenziwe ngokwezifiso eyenzelwe ngokukhethekile izikhubazi-oksijini, ehlose ukuxazulula izinkinga eziyinhloko embonini yezikhubazi-oksijini: "umthamo onganele wokumunca umoya-mpilo obangelwa ukwakheka kwezimbotshana okungalungile, impilo emfushane ngenxa yokumelana nomswakama okungalungile, nomphumela wokukhubaza-oksijini ongalingani ngenxa yokusabalala okungalungile". Ngokusekelwe ekulawuleni okunembayo kosayizi wezinhlayiya zesayizi we-nano nokwakheka kwezimbotshana, kuhlanganiswe nezinqubo zokulungiselela ezithuthukisiwe njengendlela ye-sol-gel kanye nobuchwepheshe obuthuthukisiwe bokugaya umoya, lo mkhiqizo awuxazululi kuphela izinkinga eziyinhloko ze-silicon dioxide yakudala ezinhlelweni zezikhubazi-oksijini kodwa futhi unokusebenza okuhle kakhulu kokusiza ukumunca umoya-mpilo, ukumelana nomswakama, nokuzinza kwezakhiwo. Ivame ukusetshenziswa ekudleni, emithini, ekudleni kwezilwane, ezintweni zikagesimende, kumathuluzi anembayo nezinye izindawo ezidinga ukukhubaza-oksijini nokugcina, futhi ithunyelwa eYurophu, eMelika, eNingizimu-mpumalanga Asia naseMiddle East kanye nezinye izimakethe zamazwe ngamazwe. II. Izinzuzo Eziyinhloko Zomkhiqizo 1. Ukwakheka Kwezimbotshana Okuthuthukisiwe kanye Nomthamo Omkhulu Wokusiza Ukumunca Umoya-mpilo Lo mkhiqizo unendawo eqondile (≥400 m²/g) nokwakheka kwezimbotshana okungalawulwa (ububanzi bezimbotshana 3-60 nm), okungakwazi ukumunca kahle umswakama emvelweni ngenkathi kuhlinzekwa ngesithwali esizinzile sezinto ezikhubaza-oksijini (njengempuphu yensimbi, i-activated carbon), kuthuthukisa kakhulu ukusebenza nokumunca umoya-mpilo kwe-deoxidizer. Indlela yayo eyinhloko isekelwe ekusebenziseni indlela ye-template kanye nendlela ye-sol-gel ethuthukisiwe ukulawula ngokunembayo inqubo yokuqala nokukhula kwamatshe amatshe e-silica, ukufeza ukufanisana okunembayo komthamo wezimbotshana nokusatshalaliswa kwezimbotshana nezinhlelo ezahlukene zezikhubazi-oksijini. Lokhu kuthuthukisa ngempumelelo indawo yokuxhumana phakathi kwezinto ezikhubaza-oksijini nomoya-mpilo, kusheshe isivinini sokuphendula sokukhubaza-oksijini, futhi kuqinisekise umphumela osheshayo nowonke wokukhubaza-oksijini. 2. Ukuhlanzeka Okuphezulu Nokumelana Nomswakama Okuhle Kakhulu Ngokulandela ngokuqinile izidingo eziphakeme zezinto ezisizayo zezikhubazi-oksijini, lo mkhiqizo unokuhlanzeka okungu-≥99% kanye nokuqukethwe okuphansi kakhulu kwezinto ezingcolile (insimbi esindayo lead ≤0.001%, arsenic ≤0.0003%), okuhambisana ngokuphelele namazinga okudla okuphezulu, imithi, kanye namazinga aphezulu omhlaba. Yonke inqubo yokukhiqiza isebenzisa ukuvikelwa kwegesi elingenamoya kanye nobuchwepheshe bokulungiselela izinto zokusetshenziswa eziphakeme kakhulu, okugwema ngokuyisisekelo ukungeniswa kwezinhlayiya ezingcolile ezingathinta umphumela wokukhubaza-oksijini noma zibangele ukungcola. Inokumelana nomswakama okuhle kakhulu nokuzinza kwemvelo, ingagcina ubuqotho bezakhiwo endaweni enomswakama (umswakama ohlobene ≤80%), ayimunci umswakama futhi ayihlangani, futhi iqinisekisa ngempumelelo ukusebenza okuzinzile kwesikhathi eside kwe-deoxidizer. 3. Ukusabalala Okuhle Kakhulu kanye Nokuhambisana Nezinto Ezikhubaza-oksijini Ngokusekelwe ekusatshalalisweni okuthuthukisiwe kosayizi wezinhlayiya zesayizi we-nano (D50=2-12 μm) nobuchwepheshe bokuguqula ubuso, lo mkhiqizo unokusebenza okuhle kakhulu kokusabalala futhi ungahlanganiswa ngokulinganayo nezinto ezahlukahlukene ezikhubaza-oksijini (njengempuphu yensimbi, i-activated carbon, i-zeolite, njll.). Ingakha uhlelo lokusabalala oluzinzile ngezinto ezikhubaza-oksijini, igweme ngempumelelo ukuhlanganiswa kwezinto ezikhubaza-oksijini ngesikhathi sokugcina nokusebenzisa, iqinisekise ukuthi zonke izinto ezikhubaza-oksijini zingathintana ngokugcwele nomoya-mpilo. Kuthuthukisa izinga lokusetshenziswa kwezinto ezikhubaza-oksijini ngaphezu kuka-35%, futhi kuqinisekisa ukulingana nokuzinza komphumela wokukhubaza-oksijini kuso sonke isikhala sokupakisha. 4. Amandla Okwenza Ngokwezifiso Avumelayo Isekela izinsizakalo zokwenza ngokwezifiso ezibhekiswe kubantu ngamapharamitha ayinhloko njengosayizi wezinhlayiya (2-100 μm), indawo eqondile (300-900 m²/g) nokwakheka kwezimbotshana (3-100 nm). Ngokwezici zenqubo nezidingo zokusebenza zezimo ezahlukene zokusebenzisa izikhubazi-oksijini (njengokupakisha ukudla, ukupakisha imithi, ukugcina izinto zikagesimende, ukugcina izinto zokudla kwezilwane), ihlinzeka ngezixazululo zomkhiqizo ezivumelana kakhulu. Ngokwesibonelo, ezikhubazini-oksijini zokudla, ingenza ngokwezifiso i-silica enosayizi omncane wezinhlayiya, ehlanzekile ukuze kuqinisekiswe ukuphepha nokusabalala; ezikhubazini-oksijini zezinto zikagesimende, inganikeza imikhiqizo evimbela umswakama futhi ezinzile kakhulu ukugwema ukulimala komswakama ezintweni zikagesimende. 5. Isiqinisekiso Sesevisi Yezobuchwepheshe Yesigaba Esigcwele Inikeza ukwesekwa kwezobuchwepheshe okuyindawo eyodwa okuhlanganisa ngaphambi kokuthengisa, ngesikhathi sokuthengisa, nangemva kokuthengisa. Ngaphambi kokuthengisa, inganikeza izinsizakalo zokuhlola amasampula enziwe ngokwezifiso kanye nokuhlola ukusebenza kokukhubaza-oksijini; ngesikhathi sokuthengisa, inikeza isiqondiso sezobuchwepheshe ngesilinganiso sokuhlanganisa sezinto ezikhubaza-oksijini ne-silica, kanye nesiqondiso senqubo yokusebenzisa; ngemva kokuthengisa, ithimba lochwepheshe le-R&D lilandelela umphumela wokusebenzisa, lixazulule izinkinga zobuchwepheshe njengokuncipha kokusebenza kokukhubaza-oksijini nokuhlanganiswa, futhi luthuthukise amapharamitha omkhiqizo ngokusekelwe kumpendulo yomsebenzisi ukuze kuqinisekiswe ukusebenza okuphezulu kwe-deoxidizer. III. Isiqinisekiso Samandla Okukhiqiza I-Shandong Zhonglian Chemistry Co., Ltd., eyasungulwa ngo-2022, iyibhizinisi lobuchwepheshe obuphezulu eligxile ku-R&D kanye nokukhiqizwa kwezinto zamakhemikhali eziphakeme, enamalungelo okungenisa nokuthekelisa azimele kanye nezitifiketi eziningi (kuhlanganise nesitifiketi somkhiqizo wokudla, imithi). Le nkampani inezimvume ezimbili eziyinhloko emkhakheni wokulungiswa kwe-silica, okuhlanganisa idivayisi yokugaya umoya ephezulu yokukhiqizwa kwe-silica kanye nohlelo oluhlakaniphile lokuthuthukisa izinqubo zokuphendula kwe-electrochemical, okunikeza ukwesekwa okuqinile kwezobuchwepheshe ekuthuthukisweni kwekhwalithi yomkhiqizo. Isisekelo sokukhiqiza samukela ukulawulwa kwenqubo ecwengisiswe kahle, sihlinzekwa ngemishini yokuhlola ethuthukisiwe njenge-laser particle size analyzers, i-specific surface area and pore size analyzers, kanye ne-X-ray fluorescence spectrometers, futhi senze izinqubo zokuhlola ezigcwele eziyi-18 ezihlanganisa ukuhlanzwa kwezinto zokusetshenziswa, ukuhlanganiswa kwesikhashana kuze kube ukuhlolwa komkhiqizo oqediwe. Ithole isitifiketi sohlelo lokuphatha ikhwalithi lwe-ISO9001 kanye nesitifiketi sokuphepha sokudla, ukufeza ukulawulwa okujwayelekile kuyo yonke iketango kusuka ku-R&D, ukukhiqiza kuze kube ukuhlolwa kwekhwalithi. IV. Izincazelo Zokupakisha Nokuthutha 1. Izincazelo Zokupakisha Ezijwayelekile Ukusebenzisa umklamo wokupakisha ojwayelekile ohambisana nezidingo zokupakisha zokudla nemithi, okunikeza izinketho zokupakisha izikhwama zamaphepha e-kraft ezingama-25kg kanye namadili e-galvanized iron angama-50kg ukuze kuhlangatshezwane nezidingo ezahlukene zenani le-oda nokuthutha. Izinto zokupakisha zenziwe ngezinto ezingenasici, ezinganobuthi futhi ezingangcoli ukuze kugwenywe ukuxhumana namakhemikhali nomkhiqizo futhi kuqinisekiswe ukuphepha nokuhlanzeka komkhiqizo. 2. Umklamo Ochwepheshe Wokuvimbela Umswakama Nokuvimbela Ukungcola Ukuze kuqinisekiswe ukuzinza komkhiqizo ngesikhathi sokuthutha nokugcina, kusebenziswe isixazululo sokuvikela esiphindwe kabili: ungqimba lwangaphakathi lusebenzisa ifilimu ye-PE yokudla enobubanzi obungu-≥0.08mm ukuze kuvalwe umswakama, kanti ungqimba lwangaphandle lusebenzisa izikhwama ezilukiwe eziqinile noma amadili e-galvanized iron ukuze kuvikelwe ukushayisana nokungcola. Emikhiqizweni ethunyelwa kwamanye amazwe, kusetshenziswa ukupakisha kwe-vacuum + ukuthunyelwa kwesitsha ukuze kugwenywe ukungena komswakama nokungcola okuhlangene ngesikhathi sokuthutha ibanga elide, kuqinisekiswe ukuthi umkhiqizo ugcina ukusebenza kwawo kwasekuqaleni lapho ufika kumakhasimende. 3. Izidingo Zokugcina Nokuthutha - Izimo zokugcina: Kufanele zigcinwe endaweni epholile, eyomile futhi enomoya omuhle, kugwenywe ukukhanya kwelanga okuqondile, izinga lokushisa eliphezulu (≥40℃) kanye nendawo enomswakama (umswakama ohlobene ≤70%), futhi kufanele zigcinwe ngokuhlukile nezinto ezivutha kalula, izinsipho ezinamandla nezi-alkali; - Impilo yeshalofu: izinyanga ezingama-36 ngaphansi kwezimo zokugcina ezifanele; - Izici zokuthutha: Lo mkhiqizo uyikhemikhali engadali ingozi, usekela ukuthunyelwa ngolwandle, ngomhlaba, ngomoya nezinye izindlela zokuthutha, futhi ungadluliselwa ngokuphepha ezindaweni ezibekwe ngamakhasimende asekhaya nawangaphandle. Ngesikhathi sokuthutha, kuyadingeka ukugwema ukushayisana okunodlame, imvula nomswakama. 4. Ukulebula Okujwayelekile Wonke umthwalo womkhiqizo uphethwe uphawulwe ngemininingwane yomkhiqizo njengobubhalo besikhubazi-oksijini, ukuhlanzeka, indawo eqondile, usayizi wezimbotshana, inombolo yomthwalo wokukhiqiza kanye nempilo yeshalofu; ngesikhathi esifanayo, ngokwemibandela yemithetho yezimakethe ezahlukene zokuthekelisa kanye nezindawo zokusebenzisa (ukudla, imithi), izilebula zezilimi eziningi kanye namashidi emininingwane yokuphepha (SDS) angalungiswa ngokwezifiso ukuze kuqinisekiswe ukuhambisana namazinga okufinyelela emakethe endawo kanye nemithetho yokuphepha. V. Izindawo Zokusebenzisa Ezisebenzayo Lo mkhiqizo usetshenziswa kabanzi emkhakheni wezikhubazi-oksijini, uhlanganisa izimboni eziningi nezigameko ezidinga ukukhubaza-oksijini, ukuvimbela umswakama nokugcina: 1. Imboni Yokudla Isetshenziswa njengento esizayo yezikhubazi-oksijini zokudla, esebenza ezintweni ezibhakiwe, amantongomane, izithelo ezomisiwe, imikhiqizo yenyama, amaswidi, imikhiqizo yezinhlamvu namafutha, njll. Isiza izinto ezikhubaza-oksijini ukuba zikwazi ukumunca ngokushesha umoya-mpilo esikhwameni, igweme ukubola kokudla, ukubola, ukushintsha umbala nokubola, yandise impilo yokudla izikhathi ezi-2-3, futhi igcine ukunambitheka kwasekuqaleni kanye nekhwalithi yokudla. 2. Imboni Yemithi Isetshenziswa ezikhubazini-oksijini zokupakisha imithi, okuhlanganisa amaphilisi, amakhasimende, izimpushana, imijovo nezinye izinto zemithi. Ingakwazi ukususa ngempumelelo umoya-mpilo esikhwameni, igweme ukubola kwezithako zemithi, iqinisekise ukusebenza nokuzinza kwemithi, futhi ihlangabezane nezidingo eziqinile zekhwalithi zemboni yemithi. 3. Imboni Yokudla Kwezilwane Isetshenziswa njengento esizayo yezikhubazi-oksijini zokudla kwezilwane, esebenza ezinhlobonhlobo zokudla okuhlanganisiwe, izithako zokudla kwezilwane kanye nokudla kwezilwane zasemanzini. Ivimbela ukubola kokudla kwezilwane, ukubola nokulahleka kwezakhiwo ngesikhathi sokugcina, ithuthukisa ikhwalithi yokudla kwezilwane, futhi igweme izifo zezilwane ezibangelwa ukudla kwezilwane okubolile. 35. Imboni Yezinto Zikagesimende Namathuluzi Anembayo Isetshenziswa ezikhubazini-oksijini zezinto zikagesimende namathuluzi anembayo (njengama-chip, izinzwa, amamitha anembayo). Ayisusi kuphela umoya-mpilo esikhwameni ukuze kugwenywe ukugqwala kwezingxenye zensimbi kodwa futhi inokusebenza okuhle kakhulu kokuvimbela umswakama, igweme ukulimala komswakama ezintweni zikagesimende namathuluzi anembayo, iqinisekise ukusebenza kwayo okujwayelekile kanye nempilo yesevisi. VI. Isiphetho I-silicon dioxide ye-Shandong Zhonglian Chemistry eyenzelwe izikhubazi-oksijini ibekwe enkabeni ye-"ukuthuthukisa ukusebenza kokukhubaza-oksijini, ukwandisa isikhathi sokugcina nokuqinisekisa ukuphepha komkhiqizo". Ngokusekelwe kubuchwepheshe bokulungiselela obusha, uhlelo oluqinile lokulawula ikhwalithi kanye nethimba lezobuchwepheshe eliqeqeshiwe, lihlinzeka ngezixazululo eziyindawo eyodwa zezikhubazi-oksijini ezinkampanini ezimbonini zokudla, zemithi, zezilwane, zikagesimende nezinye izimboni. Le nkampani izibophezele ekuthuthukiseni imboni yezikhubazi-oksijini ngemikhiqizo esezingeni eliphezulu futhi yamukela ngobuqotho imibuzo kanye nokubambisana okuvela kumakhasimende asekhaya nawangaphandle.