I. Isingeniso Somkhiqizo Lo mkhiqizo uyisikhubazi-oksijini esisebenza kakhulu esenziwe nge-silicon dioxide esithuthukiswe ngokuzimela yiShandong Zhonglian Chemistry Co., Ltd. Kuyinto esetshenziswa ngokwezifiso eyenzelwe ngokukhethekile izikhubazi-oksijini, ihlose ukuxazulula izinkinga eziyinhloko embonini yezikhubazi-oksijini: "umthamo onganele wokumunca umoya obangelwa ukwakheka kwezimbotshana okungalungile, impilo emfushane ngenxa yokumelana nomswakama okungalungile, nomphumela wokukhubaza-oksijini ongalingani ngenxa yokusabalala okungalungile". Ngokusekelwe ekulawuleni okunembayo kosayizi wezinhlayiya zesayensi ye-nano nokwakheka kwezimbotshana, kuhlanganiswe nezinqubo zokulungiselela ezithuthukile njengendlela ye-sol-gel kanye nobuchwepheshe bokugaya umoya obuhle kakhulu, lo mkhiqizo awuxazululi kuphela izinkinga eziyinhloko ze-silicon dioxide yakudala ekusetshenzisweni kwezikhubazi-oksijini kodwa futhi unokusebenza okuhle kakhulu kokusiza ukumunca umoya, ukumelana nomswakama, nokuqina komqulu. Isetshenziswa kabanzi ekudleni, emithini, ezifuyweni, ezintweni zikagesi, kumishini enembayo nezinye izindawo ezidinga ukukhubaza-oksijini nokugcina, futhi ithunyelwa eYurophu, eMelika, eNingizimu-mpumalanga Asia naseMiddle East nezinye izimakethe zamazwe ngamazwe. II. Izinzuzo Eziyinhloko Zomkhiqizo 1. Ukwakheka Kwezimbotshana Okuhlelekile Nomthamo Omkhulu Wokusiza Ukumunca Umoya Lo mkhiqizo unendawo eqondile (≥400 m²/g) nokwakheka kwezimbotshana okulawulekayo (ububanzi bezimbotshana 3-60 nm), okungakwazi ukumunca kahle umswakama emoyeni ngenkathi unikeza isikhubekiso esizinzile sezinto ezikhubaza-oksijini (njenge-iron powder, i-activated carbon), kuthuthukisa kakhulu ukusebenza nomthamo wokumunca umoya wesikhubazi-oksijini. Indlela yayo eyinhloko isekelwe ekusebenziseni indlela ye-template kanye nendlela ye-sol-gel ethuthukisiwe ukulawula ngokunemba inqubo yokuqala nokukhula kwamakristalu e-silica, ukufeza ukufanisana okunembayo komthamo wezimbotshana nokusatshalaliswa kwezimbotshana nezinhlelo ezahlukene zezikhubazi-oksijini. Lokhu kuthuthukisa ngempumelelo indawo yokuxhumana phakathi kwezinto ezikhubaza-oksijini nomoya, kushesisa isivinini sokuphendula sokukhubaza-oksijini, futhi kuqinisekisa umphumela osheshayo nowonke wokukhubaza-oksijini. 2. Ubumsulwa Obuphezulu Nokumelana Nomswakama Okuhle Kakhulu Ngokulandela ngokuqinile izidingo eziphakeme zezinto ezisiza izikhubazi-oksijini, lo mkhiqizo unobumsulwa obungu-≥99% nokuqukethwe okuphansi kakhulu kwezinto ezingcolile (insimbi esindayo i-lead ≤0.001%, i-arsenic ≤0.0003%), okuhambisana ngokuphelele namazinga kazwelonke okudla, amaphilisi, namazinga aphezulu aphezulu. Yonke inqubo yokukhiqiza isebenzisa ukuvikelwa ngegazi elingasebenzi kanye nobuchwepheshe bokulungiselela izinto zokusetshenziswa eziphakeme kakhulu, okugwema ngokuyisisekelo ukungeniswa kwezinhlayiya ezingcolile ezingathinta umphumela wokukhubaza-oksijini noma zibangele ukungcola. Inokumelana nomswakama okuhle kakhulu nokuqina kwemvelo, ingagcina ubuqotho bomqulu ezindaweni ezinomswakama (umswakama ohlobene ≤80%), ayimunci umswakama futhi ayihlanganisi, futhi iqinisekisa ngempumelelo ukusebenza okuzinzile kwesikhathi eside kwesikhubazi-oksijini. 3. Ukusabalala Okuhle Kakhulu Nokuhambisana Nezinto Ezikhubaza-oksijini Ngokuncika ekusatshalalisweni okuhlelekile kosayizi wezinhlayiya zesayensi ye-nano (D50=2-12 μm) nobuchwepheshe bokuguqula ubuso, lo mkhiqizo unokusebenza okuhle kakhulu kokusabalala futhi ungahlanganiswa ngokulinganayo nezinto ezahlukene ezikhubaza-oksijini (njenge-iron powder, i-activated carbon, i-zeolite, njll.). Ingakha uhlelo lokusabalala oluzinzile ngezinto ezikhubaza-oksijini, igweme ngempumelelo ukuhlanganiswa kwezinto ezikhubaza-oksijini ngesikhathi sokugcina nokusebenzisa, iqinisekisa ukuthi zonke izinto ezikhubaza-oksijini zingathintana ngokugcwele nomoya. Kuthuthukisa izinga lokusetshenziswa kwezinto ezikhubaza-oksijini ngaphezu kuka-35%, futhi kuqinisekisa ukulingana nokuqina komphumela wokukhubaza-oksijini kuyo yonke indawo yokupakisha. 4. Amandla Okwenza Ngokwezifiso Avumelayo Isekela izinsizakalo zokwenza ngokwezifiso ezibhekiswe kubantu ngamapharamitha ayinhloko njengosayizi wezinhlayiya (2-100 μm), indawo eqondile (300-900 m²/g) nokwakheka kwezimbotshana (3-100 nm). Ngokwezici zenqubo nezidingo zokusebenza zezimo ezahlukene zokusebenzisa izikhubazi-oksijini (njengokupakisha ukudla, ukupakisha imithi, ukugcina izinto zikagesi, ukugcina izifuyo), ihlinzeka ngezixazululo zomkhiqizo ezivumelana kakhulu. Ngokwesibonelo, ezikhubazini-oksijini zokudla, ingenza ngokwezifiso i-silica enosayizi omncane wezinhlayiya, enobumsulwa obuphezulu ukuze kuqinisekiswe ukuphepha nokusabalala; ezikhubazini-oksijini zezinto zikagesi, inganikeza imikhiqizo evimbela umswakama nenezinga eliphezulu lokuqina ukuze kugwenywe umonakalo obangelwa umswakama ezintweni. 5. Isiqinisekiso Sesevisi Yezobuchwepheshe Yesigaba Esigcwele Iyanikeza ukwesekwa kwezobuchwepheshe okuyisinyathelo esisodwa esihlanganisa ngaphambi kokuthengisa, ngesikhathi sokuthengisa, nangemva kokuthengisa. Ngaphambi kokuthengisa, inganikeza izinsizakalo zokuhlola amasampula enziwe ngokwezifiso kanye nokuhlola ukusebenza kokukhubaza-oksijini; ngesikhathi sokuthengisa, inikeza isiqondiso sezobuchwepheshe ngesilinganiso sokuhlanganisa sezinto ezikhubaza-oksijini ne-silica, kanye nesiqondiso senqubo yokusebenzisa; ngemva kokuthengisa, ithimba lochwepheshe le-R&D lilandelela umphumela wokusebenzisa, lixazulule izinkinga zobuchwepheshe njengokuncipha kokusebenza kokukhubaza-oksijini nokuhlanganiswa, futhi luthuthukise amapharamitha omkhiqizo ngokusekelwe kumpendulo yomsebenzisi ukuze kuqinisekiswe ukusebenza okuphelele kwesikhubazi-oksijini. III. Isiqinisekiso Samandla Okukhiqiza I-Shandong Zhonglian Chemistry Co., Ltd., eyasungulwa ngo-2022, iyibhizinisi lobuchwepheshe obuphezulu eligxile ku-R&D nokukhiqizwa kwezinto zamakhemikhali eziphakeme, elinamalungelo okungenisa nokuthumela ngaphandle azimele kanye nezitifiketi eziningi (kuhlanganise nesitifiketi somkhiqizo wokudla, nesitifiketi semithi). Le nkampani inezimvume ezimbili eziyinhloko emkhakheni wokulungiselela i-silica, okuhlanganisa idivayisi yokugaya umoya ephezulu yokukhiqiza i-silica kanye nohlelo lokuthuthukisa oluhlakaniphile lwezinqubo zokuphendula nge-electrochemical, ihlinzeka ngokwesekwa okuqinile kwezobuchwepheshe ekuthuthukisweni kwekhwalithi yomkhiqizo. Isisekelo sokukhiqiza samukela ukulawulwa kwenqubo ecolekile, sifakwe izinto zokuhlola ezithuthukile njenge-laser particle size analyzers, i-specific surface area and pore size analyzers, kanye ne-X-ray fluorescence spectrometers, futhi siye sakha izinqubo zokuhlola ezigcwele eziyi-18 ezihlanganisa ukuhlanzwa kwezinto zokusetshenziswa, ukuhlanganiswa kwesikhashana kuze kube ukuhlolwa komkhiqizo oqediwe. Sithole isitifiketi sohlelo lokuphatha ikhwalithi lwe-ISO9001 nesitifiketi sokuphepha sokudla, sifeza ukulawulwa okujwayelekile kuyo yonke iketango kusuka ku-R&D, ukukhiqiza kuze kube ukuhlolwa kwekhwalithi. IV. Izincazelo Zokupakisha Nokuthutha 1. Izincazelo Zokupakisha Ezejwayelekile Ukusebenzisa umklamo wokupakisha ojwayelekile ohambisana nezidingo zokupakisha zokudla nemithi, ihlinzeka ngezinketho zokupakisha izikhwama zephepha le-kraft eziyi-25kg kanye namadili e-galvanized iron angama-50kg ukuze kuhlangatshezwane nezidingo ezahlukene zezinamba zama-oda nezokuthutha. Izinto zokupakisha zenziwe ngezinto ezingasebenzi, ezinganobuthi, ezingangcoli ukuze kugwenywe ukusabela kwamakhemikhali nomkhiqizo futhi kuqinisekiswe ukuphepha nokumsulwa komkhiqizo. 2. Umklamo Ochwepheshe Wokuvimbela Umswakama Nokuvimbela Ukungcola Ukuze kuqinisekiswe ukuqina komkhiqizo ngesikhathi sokuthutha nokugcina, kusebenziswa isixazululo sokuvikela esiphindwe kabili: ungqimba lwangaphakathi lusebenzisa ifilimu ye-PE yokudla enobubanzi obungu-≥0.08mm ukuze kuvalwe umswakama, kanti ungqimba lwangaphandle lusebenzisa izikhwama ezilukiwe eziqinile noma amadili e-galvanized iron ukuze kuvikelwe ukushayisana nokungcola. Emikhiqizweni ethunyelwa ngaphandle, kusetshenziswa ukupakisha kwe-vacuum + ukuthunyelwa kwesitsha ukuze kugwenywe ukungena komswakama nokungcola okuhlangene ngesikhathi sokuthutha ibanga elide, kuqinisekiswe ukuthi umkhiqizo ugcina ukusebenza kwawo kwasekuqaleni lapho ufika kumakhasimende. 3. Izidingo Zokugcina Nokuthutha - Izimo zokugcina: Kufanele zigcinwe endaweni epholile, eyomile, nevundile, kugwenywe ukukhanya kwelanga okuqondile, izinga lokushisa eliphezulu (≥40℃) kanye nendawo enomswakama (umswakama ohlobene ≤70%), futhi kufanele zigcinwe ngokuhlukile nezinto ezikhubaza-oksijini, izinsipho ezinamandla, ne-alkalis; - Impilo yeshalofu: izinyanga ezingama-36 ngaphansi kwezimo zokugcina ezifanele; - Izici zokuthutha: Lo mkhiqizo uyikhemikhali engayona ingozi, usekela ukuthunyelwa ngolwandle, ngomhlaba, ngomoya nezinye izindlela zokuthutha, futhi ungadluliselwa ngokuphepha ezindaweni ezibekwe ngamakhasimende asekhaya naphesheya. Ngesikhathi sokuthutha, kuyadingeka ukugwema ukushayisana okunodlame, imvula, nomswakama. 4. Ukulebula Okujwayelekile Wonke umthwalo womkhiqizo uphethwe ngokuqinile ngolwazi lomkhiqizo njengobumsulwa bokusiza isikhubazi-oksijini, ubumsulwa, indawo eqondile, usayizi wezimbotshana, inombolo yomthwalo wokukhiqiza, kanye nempilo yeshalofu; ngesikhathi esifanayo, ngokwemibandela yemithetho yezimakethe ezahlukene zokuthumela ngaphandle nezindawo zokusebenzisa (ukudla, imithi), izilebula zezilimi eziningi kanye namashidi emininingwane yokuphepha (SDS) angalungiswa ngokwezifiso ukuze kuqinisekiswe ukuhambisana namazinga okufinyelela emakethe endawo kanye nemithetho yokuphepha. V. Izindawo Zokusebenzisa Ezisebenzayo Lo mkhiqizo usetshenziswa kabanzi emkhakheni wezikhubazi-oksijini, uhlanganisa izimboni eziningi nezigameko ezidinga ukukhubaza-oksijini, ukuvimbela umswakama, nokugcina: 1. Imboni Yokudla Isetshenziswa njengento esiza izikhubazi-oksijini zokudla, esebenza ezintweni ezibhakiwe, amantongomane, izithelo ezomisiwe, imikhiqizo yenyama, amaswidi, imikhiqizo yezinhlamvu namafutha, njll. Isiza izinto ezikhubaza-oksijini ukuthi zikwazi ukumunca umoya ngokushesha emaphaketheni, igweme ukuguga kokudla, ukubola, ukushintsha umbala, nokubola, yandise impilo yokudla izikhathi ezi-2-3, futhi igcine ukunambitheka kwezinto zokudla nekhwalithi yazo yasekuqaleni. 2. Imboni Yamaphilisi Isetshenziswa ezikhubazini-oksijini zokupakisha imithi, okuhlanganisa amaphilisi, amakhasimende, izimpushana, imijovo nezinye izinto zemithi. Ingakwazi ukususa ngempumelelo umoya emaphaketheni, igweme izithako zemithi ukuthi zingagugi futhi zilimale, iqinisekise ukusebenza nokuqina kwemithi, futhi ihlangabezane nezidingo zekhwalithi eziqinile zemboni yemithi. 3. Imboni Yezifuyo Isetshenziswa njengento esiza izikhubazi-oksijini zezifuyo, esebenza ezifuyweni ezixubile ezahlukene, izithako zezifuyo, nezifuyo zasemanzini. Ivimbela ukuguga kwezifuyo, ukubola, nokulahlekelwa kwezinto ezibalulekile ngesikhathi sokugcina, ithuthukisa ikhwalithi yezifuyo, futhi igweme izifo zezilwane ezibangelwa izifuyo ezibolile. 5. Imboni Yezinto Zikagesi Nemishini Enembayo Isetshenziswa ezikhubazini-oksijini zezinto zikagesi nemishini enembayo (njengezinhlamvu, izinzwa, imitha enembayo). Ayisusi kuphela umoya emaphaketheni ukuze igweme ukugqwala kwezingxenye zensimbi kodwa futhi inokusebenza okuhle kakhulu kokuvimbela umswakama, igweme umonakalo obangelwa umswakama ezintweni zikagesi nemishini enembayo, iqinisekisa ukusebenza kwayo okujwayelekile nempilo yayo. VI. Isiphetho I-silicon dioxide ye-Shandong Zhonglian Chemistry yezikhubazi-oksijini ibekwe enkabeni ye-"ukuthuthukisa ukusebenza kokukhubaza-oksijini, ukwandisa isikhathi sokugcina nokuqinisekisa ukuphepha komkhiqizo". Ngokuncika kubuchwepheshe bokulungiselela obusha, uhlelo oluqinile lokulawula ikhwalithi kanye nethimba lezobuchwepheshe eliqeqeshiwe, ihlinzeka ngezixazululo eziyisinyathelo esisodwa zezikhubazi-oksijini ezinkampanini zezimboni zokudla, zemithi, zezifuyo, zikagesi nezinye izimboni. Le nkampani izibophezele ekuthuthukiseni imboni yezikhubazi-oksijini ngemikhiqizo esezingeni eliphezulu futhi yamukela ngobuqotho imibuzo kanye nokubambisana okuvela kumakhasimende asekhaya naphesheya.