I. Isingeniso Somkhiqizo Lo mkhiqizo uyisikhubazi-oksijeni esisebenza kakhulu esenziwe yi-Shandong Zhonglian Chemistry Co., Ltd. Yinto esetshenziswa ngokwezifiso eyenzelwe ngokukhethekile izikhubazi-oksijeni, ehlose ukuxazulula izinkinga eziyinhloko embonini yezikhubazi-oksijeni: "umthamo onganele wokumunca umoya-mpilo ngenxa yesakhiwo sezimbotshana esibi, impilo emfushane ngenxa yokumelana nomswakama okungalungile, kanye nomphumela wokukhubaza i-oksijeni ongalingani ngenxa yokusabalala okungalungile". Ngokusekelwe ekulawuleni okunembayo kosayizi wezinhlayiya zesayizi ye-nano nesakhiwo sezimbotshana, kuhlanganiswe nezinqubo zokulungiselela ezithuthukisiwe njengendlela ye-sol-gel kanye nobuchwepheshe bokugaya umoya obulungisiwe, lo mkhiqizo awuxazululi kuphela izinkinga eziyinhloko ze-silicon dioxide yakudala ekusetshenzisweni kwezikhubazi-oksijeni kodwa futhi unokusebenza okuhle kakhulu kokusiza ukumunca umoya-mpilo, ukumelana nomswakama, nokuzinza kwesakhiwo. Isetshenziswa kabanzi ekudleni, emithini, ekudleni kwezilwane, ezintweni zikagesimende, kumishini enembayo nezinye izindawo ezidinga ukukhubaza i-oksijeni nokugcina, futhi ithunyelwa eYurophu, eMelika, eNingizimu-mpumalanga Asia naseMiddle East kanye nezinye izimakethe zamazwe ngamazwe. II. Izinzuzo Eziyinhloko Zomkhiqizo 1. Isakhiwo Sezimbotshana Esilungisiwe kanye Nomthamo Omkhulu Wokusiza Ukumunca Umoya-mpilo Lo mkhiqizo unendawo eqondile (≥400 m²/g) kanye nesakhiwo sezimbotshana esilawulwayo (ububanzi bezimbotshana 3-60 nm), esingakwazi ukumunca kahle umswakama emvelweni ngenkathi sihlinzeka ngesiphathi esizinzile sezinto ezikhubaza i-oksijeni (njengezinsimbi, ukhola olusebenzayo), kuthuthukisa kakhulu ukusebenza kahle komthamo wokumunca umoya-mpilo wesikhubazi-oksijeni. Indlela yayo eyinhloko isekelwe ekusebenziseni indlela ye-template kanye nendlela ye-sol-gel ethuthukisiwe ukulawula ngokunembayo inqubo yokuqala nokukhula kwamakristalu e-silica, ukufeza ukufanisana okunembayo komthamo wezimbotshana nokusatshalaliswa kobubanzi bezimbotshana nezinye izinhlelo zezikhubazi-oksijeni. Lokhu kuthuthukisa ngempumelelo indawo yokuxhumana phakathi kwezinto ezikhubaza i-oksijeni nomoya-mpilo, kusheshe isivinini sokuphendula sokukhubaza i-oksijeni, futhi kuqinisekise umphumela osheshayo nowonke wokukhubaza i-oksijeni. 2. Ukuhlanzeka Okuphezulu Nokumelana Nomswakama Okuhle Kakhulu Ngokulandela ngokuqinile izidingo eziphakeme kakhulu zezinto ezisiza izikhubazi-oksijeni, lo mkhiqizo uhlanzeke kakhulu (≥99%) futhi unokuqukethwe okuncane kakhulu kwezinto ezingcolile (insimbi esindayo i-lead ≤0.001%, i-arsenic ≤0.0003%), uhlangabezana ngokuphelele namazinga kazwelonke okudla, imithi, namazinga aphezulu amazwe omhlaba. Yonke inqubo yokukhiqiza isebenzisa ukuvikelwa ngegazi elingenamoya kanye nobuchwepheshe bokulungiselela izinto zokusetshenziswa eziphakeme kakhulu, okugwema ngokuyisisekelo ukungeniswa kwezinhlayiya ezingcolile ezingathinta umphumela wokukhubaza i-oksijeni noma zibangele ukungcola. Inokumelana nomswakama okuhle kakhulu nokuzinza kwemvelo, ingagcina ubuqotho besakhiwo ezindaweni ezinomswakama (umswakama ohlobene ≤80%), ayimunci umswakama futhi ayihlangani, futhi iqinisekisa ngempumelelo ukusebenza okuzinzile kwesikhathi eside kwesikhubazi-oksijeni. 3. Ukusabalala Okuhle Kakhulu Nokuhambisana Nezinto Ezikhubaza i-Oksijeni Ngokusekelwe ekusatshalalisweni kosayizi wezinhlayiya zesayizi ye-nano (D50=2-12 μm) kanye nobuchwepheshe bokuguqula ubuso, lo mkhiqizo unokusebenza okuhle kakhulu kokusabalala futhi ungahlanganiswa ngokulinganayo nezingxenye ezahlukahlukene ezikhubaza i-oksijeni (njengezinsimbi, ukhola olusebenzayo, i-zeolite, njll.). Ingakha uhlelo lokusabalala oluzinzile nezingxenye ezikhubaza i-oksijeni, igweme ngempumelelo ukuhlanganiswa kwezingxenye ezikhubaza i-oksijeni ngesikhathi sokugcina nokusetshenziswa, iqinisekise ukuthi ingxenye ngayinye ekhubaza i-oksijeni ingathintana ngokugcwele nomoya-mpilo. Ithuthukisa izinga lokusetshenziswa kwezingxenye ezikhubaza i-oksijeni ngaphezu kuka-35%, futhi iqinisekisa ukulingana nokuzinza komphumela wokukhubaza i-oksijeni kuso sonke isikhala sokupakisha. 4. Amandla Okwenza Ngokwezifiso Avumelayo Isekela izinsizakalo zokwenza ngokwezifiso ezibhekiswe kumapharamitha abalulekile njengosayizi wezinhlayiya (2-100 μm), indawo eqondile (300-900 m²/g) kanye nesakhiwo sezimbotshana (3-100 nm). Ngokwezici zenqubo nezidingo zokusebenza zezimo ezahlukahlukene zokusebenzisa izikhubazi-oksijeni (njengokupakisha ukudla, ukupakisha imithi, ukugcina izinto zikagesimende, ukugcina izinto zokudla kwezilwane), ihlinzeka ngezixazululo zomkhiqizo ezivumelana kakhulu. Isibonelo, ezikhubazini-oksijeni zokudla, ingenza ngokwezifiso i-silica enosayizi omncane wezinhlayiya, ehlanzeke kakhulu ukuze kuqinisekiswe ukuphepha nokusabalala; ezikhubazini-oksijeni zezinto zikagesimende, inganikeza imikhiqizo evimbela umswakama futhi ezinzile kakhulu ukugwema ukulimala komswakama ezintweni zikagesimende. 5. Isiqinisekiso Sesevisi Yezobuchwepheshe Yesikhathi Esigcwele Iyanikeza ukwesekwa kwezobuchwepheshe okuyindawo eyodwa okuhlanganisa ngaphambi kokuthengisa, ngesikhathi sokuthengisa, nangemva kokuthengisa. Ngaphambi kokuthengisa, inganikeza izinsizakalo zokuhlola amasampula enziwe ngokwezifiso kanye nokuhlola ukusebenza kokukhubaza i-oksijeni; ngesikhathi sokuthengisa, inikeza isiqondiso sezobuchwepheshe esihlobene nesilinganiso sokuhlanganisa sezinto ezikhubaza i-oksijeni ne-silica, kanye nesiqondiso senqubo yokusebenzisa; ngemva kokuthengisa, ithimba lochwepheshe le-R&D lilandelela umphumela wokusebenzisa, lixazulule izinkinga zobuchwepheshe njengokuncipha kokusebenza kokukhubaza i-oksijeni nokuhlanganiswa, futhi lulungise amapharamitha omkhiqizo ngokusekelwe kumpendulo yomsebenzisi ukuze kuqinisekiswe ukusebenza okuphelele kwesikhubazi-oksijeni. III. Isiqinisekiso Samandla Okukhiqiza I-Shandong Zhonglian Chemistry Co., Ltd., eyasungulwa ngo-2022, iyibhizinisi lobuchwepheshe obuphezulu eligxile ku-R&D kanye nokukhiqizwa kwezinto zamakhemikhali eziphakeme, nelungelo lokungenisa nokuthumela ngaphandle elizimele kanye nezitifiketi eziningi (kuhlanganise nesitifiketi somkhiqizo wokudla, imithi). Le nkampani inezimvume ezimbili eziyinhloko emkhakheni wokulungiswa kwe-silica, okuhlanganisa idivayisi yokugaya umoya ephezulu yokukhiqizwa kwe-silica kanye nohlelo lokulungisa oluhlakaniphile lwezinqubo zokuphendula nge-electrochemical, ihlinzeka ngokwesekwa okuqinile kwezobuchwepheshe ekuthuthukisweni kwekhwalithi yomkhiqizo. Isisekelo sokukhiqiza samukela ukulawulwa kwenqubo ecolekile, sifakwe izinto zokuhlola ezithuthukisiwe njenge-laser particle size analyzers, specific surface area and pore size analyzers, kanye ne-X-ray fluorescence spectrometers, futhi siye sakha izinqubo zokuhlola ezigcwele eziyi-18 ezihlanganisa ukuhlanzwa kwezinto zokusetshenziswa, ukuhlanganiswa kwesikhashana kuze kube ukuhlolwa komkhiqizo oqediwe. Ithole isitifiketi sohlelo lokuphatha ikhwalithi lwe-ISO9001 kanye nesitifiketi sokuphepha sokudla, siqaphela ukulawulwa okujwayelekile kuyo yonke iketango kusuka ku-R&D, ukukhiqizwa kuze kube ukuhlolwa kwekhwalithi. IV. Izincazelo Zokupakisha Nokuthutha 1. Izincazelo Zokupakisha Ezijwayelekile Ukusebenzisa umklamo wokupakisha ojwayelekile ohlangabezana nezidingo zokupakisha zokudla nemithi, ihlinzeka ngezinketho zokupakisha izikhwama zamaphepha e-kraft eziyi-25kg kanye namadreyi ensimbi agalelwe i-zinc angama-50kg ukuze kuhlangatshezwane nezidingo ezahlukene zezinani le-oda nezokuthutha. Izinto zokupakisha zenziwe ngezinto ezingenasidingo, ezinganobuthi futhi ezingangcoli ukuze kugwenywe ukusabela kwamakhemikhali nomkhiqizo futhi kuqinisekiswe ukuphepha nokuhlanzeka komkhiqizo. 2. Umklamo Ochwepheshe Wokuvimbela Umswakama Nokungcola Ukuze kuqinisekiswe ukuzinza komkhiqizo ngesikhathi sokuthutha nokugcina, kusebenziswe isixazululo sokuvikela esiphindwe kabili: umngcele wangaphakathi usebenzisa ifilimu ye-PE yokudla enobubanzi obuyi-≥0.08mm ukuze kuvalwe umswakama, kanti umngcele wangaphandle usebenzisa izikhwama ezilukiwe ezinamandla noma amadreyi ensimbi agalelwe i-zinc ukuze kuvikelwe ukushayisana nokungcola. Imikhiqizo ethunyelwa kwamanye amazwe, kusetshenziswa ukupakisha kwe-vacuum + ukuthunyelwa kwesitsha ukuze kugwenywe ukungena komswakama nokungcola okuhlangene ngesikhathi sokuthutha ibanga elide, kuqinisekiswe ukuthi umkhiqizo ugcina ukusebenza kwawo kwasekuqaleni lapho ufika kumakhasimende. 3. Izidingo Zokugcina Nokuthutha - Izimo zokugcina: Kufanele zigcinwe endaweni epholile, eyomile futhi enomoya omuhle, kugwenywe ukukhanya kwelanga okuqondile, izinga lokushisa eliphezulu (≥40℃) kanye nendawo enomswakama (umswakama ohlobene ≤70%), futhi kufanele zigcinwe ngokuhlukile nezinto ezikhubaza i-oksijeni, izinsipho ezinamandla ne-alkalis; - Impilo yeshalofu: izinyanga ezingama-36 ngaphansi kwezimo zokugcina ezifanele; - Izici zokuthutha: Lo mkhiqizo uyikhemikhali engayona ingozi, usekela ukuthunyelwa ngolwandle, ngomhlaba, ngomoya nezinye izindlela zokuthutha, futhi ungadluliselwa ngokuphepha ezindaweni ezibekwe ngamakhasimende asekhaya naphesheya. Ngesikhathi sokuthutha, kuyadingeka ukugwema ukushayisana okunamandla, imvula nomswakama. 4. Ukulebula Okujwayelekile Wonke umthwalo womkhiqizo uphethwe ngokuqinile nolwazi lomkhiqizo njengobuntu besikhubazi-oksijeni, ukuhlanzeka, indawo eqondile, ububanzi bezimbotshana, inombolo yomthwalo wokukhiqiza kanye nempilo yeshalofu; ngesikhathi esifanayo, ngokwemibandela yokulawula yezimakethe ezahlukene zokuthunyelwa kwamanye amazwe kanye nezindawo zokusebenzisa (ukudla, imithi), izilebula zezilimi eziningi kanye namashidi emininingwane yokuphepha (SDS) angalungiswa ngokwezifiso ukuze kuqinisekiswe ukuhambisana namazinga okufinyelela emakethe endawo kanye nemithetho yokuphepha. V. Izindawo Zokusebenzisa Ezisebenzayo Lo mkhiqizo usetshenziswa kabanzi emkhakheni wezikhubazi-oksijeni, uhlanganisa izimboni eziningi nezigameko ezidinga ukukhubaza i-oksijeni, ukuvimbela umswakama nokugcina: 1. Imboni Yokudla Isetshenziswa njengento esiza izikhubazi-oksijeni zokudla, esebenza ezintweni ezibhakiwe, amantongomane, izithelo ezomisiwe, imikhiqizo yenyama, amaswidi, imikhiqizo yezinhlamvu namafutha, njll. Isiza izinto ezikhubaza i-oksijeni ukuthi zimunce ngokushesha umoya-mpilo esikhwameni, igweme ukubola kokudla, ukubola, ukushintsha umbala nokubola, yandise impilo yeshalofu yokudla izikhathi ezi-2-3, futhi igcine ukunambitheka kwasekuqaleni kanye nekhwalithi yokudla. 2. Imboni Yemithi Isetshenziswa ezikhubazini-oksijeni zokupakisha imithi, okuhlanganisa amaphilisi, amakhasimende, izimpushana, imijovo nezinye izimikhiqizo zemithi. Ingakwazi ukususa ngempumelelo umoya-mpilo esikhwameni, igweme ukubola kwezithako zemithi, iqinisekise ukusebenza nokuzinza kwemithi, futhi ihlangabezane nezidingo eziqinile zekhwalithi zemboni yemithi. 3. Imboni Yokudla Kwezilwane Isetshenziswa njengento esiza izikhubazi-oksijeni zokudla kwezilwane, esebenza ezinhlobonhlobo zezinto zokudla ezihlanganisiwe, izithako zokudla kwezilwane kanye nezokudla kwezilwane zasemanzini. Ivimbela ukubola kokudla kwezilwane, ukubola kanye nokulahleka kwezakhamzimba ngesikhathi sokugcina, ithuthukisa ikhwalithi yokudla kwezilwane, futhi igwema izifo zezilwane ezibangelwa ukudla kwezilwane okubolile. 27. Imboni Yezinto Zikagesimende Nemishini Enembayo Isetshenziswa ezikhubazini-oksijeni zezinto zikagesimende nemishini enembayo (njengezinhlamvu, izinzwa, imitha enembayo). Ayisusi kuphela umoya-mpilo esikhwameni ukuze kugwenywe ukugqwala kwezingxenye zensimbi kodwa futhi inokusebenza okuhle kakhulu kokuvimbela umswakama, igweme ukulimala komswakama ezintweni zikagesimende nemishini enembayo, iqinisekise ukusebenza kwayo okujwayelekile kanye nempilo yesevisi. VI. Isiphetho I-silicon dioxide ye-Shandong Zhonglian Chemistry eyenzelwe izikhubazi-oksijeni ibekwe enkabeni ye-"ukuthuthukisa ukusebenza kokukhubaza i-oksijeni, ukwandisa isikhathi sokugcina nokuqinisekisa ukuphepha komkhiqizo". Ngokusekelwe kubuchwepheshe bokulungiselela obusha, uhlelo oluqinile lokulawula ikhwalithi kanye nethimba lezobuchwepheshe eliqeqeshiwe, lihlinzeka ngezixazululo eziyindawo eyodwa ezisiza izikhubazi-oksijeni ezinkampanini ezimbonini zokudla, zemithi, zezilwane, zikagesimende nezinye izimboni. Le nkampani izibophezele ekuthuthukiseni imboni yezikhubazi-oksijeni ngemikhiqizo esezingeni eliphezulu futhi yamukela ngobuqotho imibuzo kanye nokubambisana namakhasimende asekhaya naphesheya.