I. Isingeniso Somkhiqizo Lo mkhiqizo uyisikhubazi-oksijini esisebenza kakhulu esenziwe nge-silicon dioxide esithuthukiswe ngokuzimela yiShandong Zhonglian Chemistry Co., Ltd. Kuyinto esiza ukwenziwa ngokwezifiso eyenzelwe ngokukhethekile izikhubazi-oksijini, ihlose ukuxazulula izinkinga eziyinhloko embonini yezikhubazi-oksijini: "umthamo onganele wokumunca umoya-mpilo obangelwa ukwakheka kwezimbotshana okungalungile, impilo emfushane ngenxa yokumelana nomswakama okungalungile, kanye nomphumela wokukhubaza-oksijini ongalingani ngenxa yokusabalala okungalungile". Ngokusekelwe ekulawuleni okunembayo kosayizi wezingxenyana zesayizi we-nano nokwakheka kwezimbotshana, kuhlanganiswe nezinqubo zokulungiselela ezithuthukile njengendlela ye-sol-gel kanye nobuchwepheshe obuthuthukisiwe bokugaya umoya, lo mkhiqizo awuxazululi kuphela izinkinga eziyinhloko ze-silicon dioxide yakudala ekusetshenzisweni kwezikhubazi-oksijini, kodwa futhi unokusebenza okuhle kakhulu kokusiza ukumunca umoya-mpilo, ukumelana nomswakama, nokuqina kwezakhiwo. Usasetshenziswa kabanzi ekudleni, emithini, ekudleni kwezilwane, ezintweni zikagesi, ezinsizeni eziqine kakhulu nezinye izindawo ezidinga ukukhubaza-oksijini nokugcina, futhi uthunyelwa eYurophu, eMelika, eNingizimu-mpumalanga Asia naseMiddle East nezinye izimakethe zamazwe ngamazwe. II. Izinzuzo Eziyinhloko Zomkhiqizo 1. Ukwakheka Kwezimbotshana Okuthuthukisiwe Nomthamo Ophezulu Wokusiza Ukumunca Umoya-mpilo Lo mkhiqizo unendawo eqondile (≥400 m²/g) nokwakheka kwezimbotshana okungalawulwa (ububanzi bezimbotshana 3-60 nm), okungakwazi ukumunca kahle umswakama emvelweni ngenkathi kuhlinzekwa ngesikhundla esizinzile sezinto ezikhubaza-oksijini (njenge-iron powder, i-activated carbon), kuthuthukisa kakhulu ukusebenza nomthamo wokumunca umoya-mpilo wesikhubazi-oksijini. Indlela yayo eyinhloko isekelwe ekusebenziseni indlela ye-template kanye nendlela ye-sol-gel ethuthukisiwe ukulawula ngokunembayo inqubo yokuqala nokukhula kwamatshe amatshe e-silica, ukufeza ukufanisana okunembayo komthamo wezimbotshana nokusatshalaliswa kwezimbotshana nezinhlelo ezahlukene zezikhubazi-oksijini. Lokhu kuthuthukisa ngempumelelo indawo yokuxhumana phakathi kwezinto ezikhubaza-oksijini nomoya-mpilo, kushesisa isivinini sokuphendula sokukhubaza-oksijini, futhi kuqinisekisa umphumela osheshayo nowonke wokukhubaza-oksijini. 2. Ukuhlanzeka Okuphezulu Nokumelana Nomswakama Okuhle Kakhulu Ngokulandela ngokuqinile izidingo eziphakeme kakhulu zezinto ezisiza izikhubazi-oksijini, lo mkhiqizo unokuhlanzeka okungu-≥99% kanye nokuqukethwe okuphansi kakhulu kwezinto ezingcolile (i-heavy metal lead ≤0.001%, i-arsenic ≤0.0003%), okuhambisana ngokuphelele namazinga okudla okuphezulu, imithi, namazinga aphezulu amazwe omhlaba. Yonke inqubo yokukhiqiza isebenzisa ukuvikelwa ngegazi elingenamoya kanye nobuchwepheshe bokulungiselela izinto ezingcolile eziphakeme kakhulu, okugwema ngokuyisisekelo ukungeniswa kwezinhlayiya ezingcolile ezingathinta umphumela wokukhubaza-oksijini noma zibangele ukungcola. Inokumelana nomswakama okuhle kakhulu nokuqina kwemvelo, ingagcina ubuqotho bezakhiwo endaweni enomswakama (umswakama ohlobene ≤80%), ayimunci umswakama futhi ayihlanganisi, futhi iqinisekisa ngempumelelo ukusebenza okuzinzile kwesikhathi eside kwesikhubazi-oksijini. 3. Ukusabalala Okuhle Kakhulu Nokuhambisana Nezinto Ezikhubaza-oksijini Ngokuncika ekusabalaleni kosayizi wezingxenyana zesayizi we-nano okuthuthukisiwe (D50=2-12 μm) nobuchwepheshe bokuguqula ubuso, lo mkhiqizo unokusebenza okuhle kakhulu kokusabalala futhi ungahlanganiswa ngokulinganayo nezinto ezahlukene ezikhubaza-oksijini (njenge-iron powder, i-activated carbon, i-zeolite, njll.). Ingakha uhlelo lokusabalala oluzinzile ngezinto ezikhubaza-oksijini, igweme ngempumelelo ukuhlanganiswa kwezinto ezikhubaza-oksijini ngesikhathi sokugcina nokusebenzisa, iqinisekisa ukuthi zonke izinto ezikhubaza-oksijini zingathintana ngokugcwele nomoya-mpilo. Kuthuthukisa izinga lokusetshenziswa kwezinto ezikhubaza-oksijini ngaphezu kuka-35%, futhi kuqinisekisa ukulingana nokuqina komphumela wokukhubaza-oksijini kuso sonke isikhala sokupakisha. 4. Amandla Okwenza Ngokwezifiso Avumelayo Isekela izinsizakalo zokwenza ngokwezifiso eziyimfihlo zamapharamitha ayinhloko njengosayizi wezingxenyana (2-100 μm), indawo eqondile (300-900 m²/g) nokwakheka kwezimbotshana (3-100 nm). Ngokwezici zenqubo nezidingo zokusebenza zezimo ezahlukene zokusebenzisa izikhubazi-oksijini (njengokupakisha ukudla, ukupakisha imithi, ukugcina izinto zikagesi, ukugcina izinto zokudla kwezilwane), ihlinzeka ngezixazululo zomkhiqizo ezivumelana kakhulu. Isibonelo, ezikhubazini-oksijini zokudla, ingenza ngokwezifiso i-silica enosayizi wezingxenyana emihle, ehlanzekile ukuze kuqinisekiswe ukuphepha nokusabalala; ezikhubazini-oksijini zezinto zikagesi, inganikeza imikhiqizo evimbela umswakama futhi ezinzile kakhulu ukugwema ukulimala komswakama ezintweni zikagesi. 5. Isiqinisekiso Sesevisi Yezobuchwepheshe Yesikhathi Esigcwele Iyanikeza ukwesekwa kwezobuchwepheshe okuyindawo eyodwa okuhlanganisa ngaphambi kokuthengisa, ngesikhathi sokuthengisa, nangemuva kokuthengisa. Ngaphambi kokuthengisa, inganikeza izinsizakalo zokuhlola amasampula ngokwezifiso kanye nokuhlola ukusebenza kokukhubaza-oksijini; ngesikhathi sokuthengisa, inikeza isiqondiso sezobuchwepheshe ngesilinganiso sokuhlanganisa sezinto ezikhubaza-oksijini ne-silica, kanye nesiqondiso senqubo yokusebenzisa; ngemuva kokuthengisa, ithimba lochwepheshe le-R&D lilandelela umphumela wokusebenzisa, lixazulule izinkinga zobuchwepheshe njengokuncipha kokusebenza kokukhubaza-oksijini nokuhlanganiswa, futhi luthuthukise amapharamitha omkhiqizo ngokusekelwe kumpendulo yomsebenzisi ukuze kuqinisekiswe ukusebenza okuphezulu kwezikhubazi-oksijini. III. Isiqinisekiso Samandla Okukhiqiza I-Shandong Zhonglian Chemistry Co., Ltd., eyasungulwa ngo-2022, iyibhizinisi lobuchwepheshe obuphezulu eligxile ku-R&D nokukhiqizwa kwezinto zamakhemikhali eziphakeme, nelungelo lokungenisa nokuthumela ngaphandle elizimele kanye nezitifiketi eziningi (kuhlanganise nesitifiketi somkhiqizo wokudla, imithi). Le nkampani inezimvume ezimbili eziyinhloko emkhakheni wokulungiselela i-silica, okuhlanganisa idivayisi yokugaya umoya ephezulu yokukhiqizwa kwe-silica kanye nohlelo oluhlakaniphile lokuthuthukisa izinqubo zokuphendula nge-electrochemical, ihlinzeka ngokwesekwa okuqinile kwezobuchwepheshe ekuthuthukisweni kwekhwalithi yomkhiqizo. Isisekelo sokukhiqiza samukela ukulawulwa kwenqubo eyenziwe kahle, sifakwe izinto zokuhlola ezithuthukile njenge-laser particle size analyzers, specific surface area and pore size analyzers, kanye ne-X-ray fluorescence spectrometers, futhi siye sakha izinqubo zokuhlola ezigcwele eziyi-18 ezihlanganisa ukuhlanzwa kwezinto zokusetshenziswa, ukuhlanganiswa kwesikhashana kuze kube ukuhlolwa komkhiqizo oqediwe. Sithole isitifiketi sohlelo lokuphatha ikhwalithi lwe-ISO9001 kanye nesitifiketi sokuphepha sokudla, siqaphela ukulawulwa okujwayelekile kuyo yonke iketango kusuka ku-R&D, ukukhiqiza kuze kube ukuhlolwa kwekhwalithi. IV. Izincazelo Zokupakisha Nokuthutha 1. Izincazelo Zokupakisha Ezijwayelekile Ukusebenzisa umklamo wokupakisha ojwayelekile ohambisana nezidingo zokupakisha zokudla nemithi, kuhlinzekwa ngezinketho zokupakisha izikhwama zamaphepha e-kraft eziyi-25kg kanye namadreyi ensimbi agalelwe i-zinc angama-50kg ukuze kuhlangatshezwane nezidingo ezahlukene zezinamba zama-oda nokuthutha. Izinto zokupakisha zenziwe ngezinto ezingenasidingo, ezinganobuthi, ezingangcolisi ukuze kugwenywe ukusabela kwamakhemikhali nomkhiqizo futhi kuqinisekiswe ukuphepha nokuhlanzeka komkhiqizo. 2. Umklamo Ochwepheshile Ovimbela Umswakama Nokungcola Ukuze kuqinisekiswe ukuqina komkhiqizo ngesikhathi sokuthutha nokugcina, kusetshenziswa isixazululo sokuvikela esiphindwe kabili: umngcele wangaphakathi usebenzisa ifilimu ye-PE yokudla enobubanzi obungu-≥0.08mm ukuze kuvalwe umswakama, kanti umngcele wangaphandle usebenzisa izikhwama ezilukiwe ezinamandla noma amadreyi ensimbi agalelwe i-zinc ukuze kuvikelwe ukushayisana nokungcola. Emikhiqizweni ethunyelwa ngaphandle, kusetshenziswa ukupakisha kwe-vacuum + ukuthunyelwa kwesitsha ukuze kugwenywe ukungena komswakama nokungcola okuhlangene ngesikhathi sokuthutha ibanga elide, kuqinisekiswe ukuthi umkhiqizo ugcina ukusebenza kwawo kwasekuqaleni lapho ufika kumakhasimende. 3. Izidingo Zokugcina Nokuthutha - Izimo zokugcina: Kufanele zigcinwe endaweni epholile, eyomile futhi enomoya omuhle, kugwenywe ukukhanya kwelanga okuqondile, izinga lokushisa eliphezulu (≥40℃) kanye nendawo enomswakama (umswakama ohlobene ≤70%), futhi kufanele kugcinwe ngokuhlukile nezinto ezibangela ukubola, izinsipho ezinamandla nezi-alkali; - Impilo yeshalofu: izinyanga ezingama-36 ngaphansi kwezimo zokugcina ezifanele; - Izici zokuthutha: Lo mkhiqizo uyikhemikhali engadali ingozi, usekela ukuthunyelwa ngolwandle, ngomhlaba, ngomoya nezinye izindlela zokuthutha, futhi ungadluliselwa ngokuphepha ezindaweni ezibekwe ngamakhasimende asekhaya naphesheya. Ngesikhathi sokuthutha, kuyadingeka ukugwema ukushayisana okunamandla, imvula nomswakama. 4. Ukulebula Okujwayelekile Wonke umthwalo womkhiqizo wokupakisha uphawulwe ngokuqinile ngolwazi lomkhiqizo njengobuntu besikhubazi-oksijini, ukuhlanzeka, indawo eqondile, usayizi wezimbotshana, inombolo yomthwalo wokukhiqiza kanye nempilo yeshalofu; ngesikhathi esifanayo, ngokwemibandela yokulawula yezimakethe ezahlukene zokuthunyelwa ngaphandle kanye nezindawo zokusebenzisa (ukudla, imithi), izilebula zezilimi eziningi kanye namashidi emininingwane yokuphepha (SDS) angakwenziwa ngokwezifiso ukuze kuqinisekiswe ukuhambisana namazinga okufinyelela emakethe endawo kanye nemithetho yokuphepha. V. Izindawo Zokusebenzisa Ezisebenzayo Lo mkhiqizo usetshenziswa kabanzi emkhakheni wezikhubazi-oksijini, uhlanganisa izimboni eziningi nezinye izimo ezidinga ukukhubaza-oksijini, ukuvimbela umswakama nokugcina: 1. Imboni Yokudla Usasetshenziswa njengento esiza izikhubazi-oksijini zokudla, ezisebenza ezintweni ezibhakiwe, amantongomane, izithelo ezomisiwe, imikhiqizo yenyama, amaswidi, imikhiqizo yezinhlamvu namafutha, njll. Kusiza izinto ezikhubaza-oksijini ukuthi zikwazi ukumunca ngokushesha umoya-mpilo esikhwameni, kugwenywe ukubola kokudla, ukubola, ukushintsha umbala nokubola, kwandiswe impilo yeshalofu yokudla izikhathi ezi-2-3, futhi kugcinwe ukunambitheka kwezinto zokudla nekhwalithi yazo yasekuqaleni. 2. Imboni Yemithi Usasetshenziswa ezikhubazini-oksijini zokupakisha imithi, okuhlanganisa amaphilisi, amakhepsuli, izimpushana, imijovo nezinye izinto zemithi. Kungakwazi ukususa ngempumelelo umoya-mpilo esikhwameni, kugwenywe ukubola kwezithako zemithi, kuqinisekiswe ukusebenza nokuzinza kwemithi, futhi kuhlangatshezwane nezidingo zekhwalithi eziqinile zemboni yemithi. 3. Imboni Yokudla Kwezilwane Usasetshenziswa njengento esiza izikhubazi-oksijini zokudla kwezilwane, ezisebenza ezinhlobonhlobo zokudla okuhlanganisiwe, izithako zokudla kwezilwane kanye nokudla kwezilwane zasemanzini. Kuvimbela ukubola kokudla kwezilwane, ukubola nokulahlekelwa kwezakhamzimba ngesikhathi sokugcina, kuthuthukisa ikhwalithi yokudla kwezilwane, futhi kugwema izifo zezilwane ezibangelwa ukudla kwezilwane okubolile. 21. Imboni Yezinto Zikagesi Nezinsizakalo Eziqine Kakhulu Usasetshenziswa ezikhubazini-oksijini zezinto zikagesi nezinsizakalo eziqine kakhulu (njengezinhlamvu, izinzwa, izilinganiso eziqine kakhulu). Akusona kuphela ukuthi kususa umoya-mpilo esikhwameni ukuze kugwenywe ukubola kwezingxenye zensimbi, kodwa futhi kunezinga elihle kakhulu lokuvimbela umswakama, kugwenywe ukulimala komswakama ezintweni zikagesi nezinsizakalo eziqine kakhulu, kuqinisekiswe ukusebenza kwazo okujwayelekile kanye nempilo yazo. VI. Isiphetho I-silicon dioxide ye-Shandong Zhonglian Chemistry esetshenziselwa izikhubazi-oksijini ibekwe enkabeni ye-"ukuthuthukisa ukusebenza kokukhubaza-oksijini, ukwandisa isikhathi sokugcina nokuqinisekisa ukuphepha komkhiqizo". Ngokuncika kubuchwepheshe bokulungiselela obusha, uhlelo oluqinile lokulawula ikhwalithi kanye nethimba lochwepheshe lezinsizakalo, ihlinzeka ngezixazululo eziyindawo eyodwa zezinto ezisiza izikhubazi-oksijini ezinkampanini ezimbonini zokudla, zemithi, zezokudla kwezilwane, nezikagesi nezinye izimboni. Le nkampani izibophezele ekuthuthukiseni imboni yezikhubazi-oksijini ngemikhiqizo esezingeni eliphezulu futhi yamukela ngobuqotho imibuzo kanye nokubambisana okuvela kumakhasimende asekhaya naphesheya.